(Solved): In radical chlorination of alkanes, nonequivalent hydrogens react with chlorine atoms at different ...

In radical chlorination of alkanes, nonequivalent hydrogens react with chlorine atoms at different rates. At $$35^{?}\mathrm{C}$$, primary, secondary, and tertiary $$\mathrm{C}?\mathrm{H}$$ bonds react at relative rates of $$1:3.9$$ : 5.2 respectively. These are conditions of kinetic control where product ratios are determined by relative rates of formation. For example, if $$A$$ is formed twice as fast as $$B$$, the $$A:B$$ product ratio will be 2 . Consider chlorination of the alkane below at $$35^{?}\mathrm{C}$$. 1. Specify the most reactive $$\mathrm{C}?\mathrm{H}$$ bond(s), a-c. Two non-equivalent $$\mathrm{C}?\mathrm{H}$$ bonds of comparable reactivity should be separated by commas, i.e. a,c. 2. Specify the site of chlorination in the major monochloro substitution product, a-c. Two products that form in comparable quantities should be separated by commas, i.e. $$a,c$$ 1. Specify the most reactive $$\mathrm{C}?\mathrm{H}$$ bond(s), a-c. Two non-equivalent $$\mathrm{C}?\mathrm{H}$$ bonds of comparable reactivity should be separated by commas, i.e. a,c. 2. Specify the site of chlorination in the major monochloro substitution product, a-c. Two products that form in comparable quantities should be separated by commas, i.e. $$a,c$$ 1. Specify the most reactive $$\mathrm{C}?\mathrm{H}$$ bond(s), a-c. Two non-equivalent $$\mathrm{C}?\mathrm{H}$$ bonds of comparable reactivity should be separated by commas, i.e. a,c. 2. Specify the site of chlorination in the major monochloro substitution product, a-c. Two products that form in comparable quantities should be separated by commas, i.e. $$a,c$$