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For each of the 7 types of reactions (addition, dissociation, oxidative addition, reductive elimin ...
For each of the 7 types of reactions (addition, dissociation, oxidative addition, reductive elimination, 1,2-migratory insertion, ß-elimination, and carbonyl insertion), assess how the following properties change (if at all) in order to answer questions a-i below: ------- Coordination number Oxidation state of the metal • Total electron count around the metal Reductive Elimination a. RH (H?) LM -R (H) H LM RH (H-H) - The ligands (-R, -H) may be in cis or trans configuration, based on the mechanism involved (concerted or stepwise). We will not cover the mechanism. b. RX (HX) LM -R (H) -X LMR-X (H-X) - The ligands (-R, -X) may be in cis or trans configuration, based on the mechanism involved (concerted or stepwise). We will not cover the mechanism. 1,2-Migratory Insertion 1CR? RR || 2CR? LM LM -C¹-C²-H H R R - The ligands (H and C?R4) must be in cis configuration. B-Elimination CR? R R L?M C—C—H L?M RR Carbonyl Insertion -CR3 CR? L?M LM -CR3 CO - The ligands (CO and -CR3) must be in cis configuration. ·|| CR?