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(Solved): (a) Fluorenone (the impurity added to both the sulfanilamide and the fluorene) has a melting p ...



(a) Fluorenone (the “impurity” added to both the sulfanilamide and the fluorene) has a melting point of 84 ºC. How would you expect the melting point of the impure (pre-crystallization) sulfanilamide (M.P. 166 ºC) to be different if the 5% impurity were trans-cinnamic acid (MP 133 ºC) instead of fluorenone? What about the melting point of the impure fluorene (M.P. 116 ºC)?

(b) Would you expect that changing the initial 5% impurity to trans-cinnamic acid have any effect on the melting point ranges of your purified sulfanilamide and/or fluorene? If so, how would you anticipate the melting point range to be different? If not, why not?



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Answer:(a) The melting point of the impure sulfanilamide (M.P. 166 ºC) would be expected to decrease if the 5% impurity were trans-c
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