4. Pb(s)PbSO4(s)Hg2SO4 (s) Hg(l) (a) Write the cell reaction and electrode half-reactions. Calculate (b) the standard cell potential, (c) equilibrium constant of the cell, and (c) rG,rH, and rS at 25C. The temperature coefficient of the cell potential is 1.74104VK1. R=8.314Jmol1K1,F=96485Cmol1 PbSO4

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4. Pb(s)PbSO4(s)Hg2SO4 (s) Hg(l) (a) Write the cell reaction and electrode half-reactions. Calculate (b) the standard cell potential, (c) equilibrium constant of the cell, and (c) rG,rH, and rS at 25C. The temperature coefficient of the cell potential is 1.74104VK1. R=8.314Jmol1K1,F=96485Cmol1 PbSO4+2ePb+SO42Hg2SO4+2e2Hg+SO42E=0.36VE=+0.62V

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